benzilic acid hazards

/Subtype /Link Benzilic acid does not contain chromophores that absorb at wavelengths >290 nm and therefore is not expected to be susceptible to direct photolysis by sunlight. endobj endobj Add 90 ml rectified spirit and 35 g benzil and reflux the content on a water bath till blue colour disappears (10-15 min). Section 3: Hazards Identification Potential Acute Health Effects: Very hazardous in case of skin contact /Resources 3 0 R endobj endstream 1 0 obj 7.3. It is used in manufacture of the incapacitating agent 3-quinuclidinyl benzilate (BZ) and is regulated by the Chemical Weapons … Potential Acute Health Effects: Very hazardous in case of skin contact (irritant), of eye contact (irritant). Benzilic Acid 76-93-7 100 Toxicological Data on Ingredients: Benzilic Acid: ORAL (LD50): Acute: 2000 mg/kg [Mouse]. 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>> 14 0 obj The CLP Regulation ensures that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union through classification and labelling of chemicals. /MediaBox [ 0 0 612 792 ] Do not eat, drink or smoke when … ] stream Keep container tightly sealed.Store with like hazards /Parent 1 0 R May cause respiratory and digestive tract irritation. /Parent 1 0 R * (Pharmacology & Toxicology, 2009) Predict GHS Hazards for Any Chemical in silico. stream /Parent 1 0 R Benzilic acid Catalog No. "pu356~> "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��“7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k�������u��=���� ��f.�蟗��y_�j6}Yɗ���2�3 �> q�B�-��i����%�m���Si��=�J�����������uL�Ã{��!��B�431 �� \�~��iww�#⽯��������$��&I���=�u�s��=�(��#�������������O����O�i p�8=��˶8/�Y[T˯;2�=��dL�;;L��u5[O��E�ȿ�>��v�\O������ٴ�}s��@������Q��G�\: << /Type /Info Most-cited Publications The Effect of Benzilic Acid Diethylaminoethylester, HCl (Benactyzine) on Stress-Induced Behaviour in the Rat. 15 0 obj << /Length 1621 /Filter [ /ASCII85Decode /FlateDecode ] /Producer(Sub Systems, Inc.)/CreationDate(D:20200214112341+05'00')/ModDate(D:20200214112341+05'00')/Creator(Sub Systems, Inc.) /Parent 1 0 R /Contents 12 0 R [ /MediaBox [ 0 0 612 792 ] The other preparation way is through benzaldehyde, which dimerizates to benzil and it is further transformed by benzilic acid rearrangement to benzilic acid. Product name : Sebacic Acid CAS-No. Editor's note: Some chemicals in this database contain more information than others due to the original reason this information was collected and how the compilation was … endstream /A << /URI (http://www.sciencelab.com/) It can be prepared by heating mixture of benzil, alcohol and potassium hydroxide. Hazards not otherwise classified (HNOC) None identified 3. (Ot[(HL)2lLq_#hA6K1H(A>7I_JR.W64_I&fhOe*2T7&l/C;/BIX[-'mrU[D/r:OM"oG!35oq,]/?,P9u89%VU0WkaNNi_bJsZVMg6_MNJ5,XUH.m]'!s'E)6S`lhlNp2CCps7CchD;,h%H;om,[.jgD1@$QgZI-SKNAoi%5$qon#Lf8"(u$1_#8re,=7'+m$"$^U,^Ap]YT'?Ih6)9me,q^s_:\D/"6E259.djSqLKWSdG*#JP9SJ'&\MH!R:"R4O76*3.#p5)&.CjNlblq3NfD%3^)mq88tjca=\$##DIFI)cOeXa[(pFF;Gm,FdEIbQRh>j4Z&HTH;ikg=-%[b=]2)Tk3nMc:J#fdPA:T!Apcj4D!#*r3gSq;I+G6g@%=8D?H!B?,bt$T_B.hVCWr=-7(-Z^Uk*;koIbYKWFMI%]6_rM\;&BP#,RBAmBP9Q]^3,-*k]ji@mcNJU.2j,X"%]r'^,$ZDB[tafH6^g>p8QI7d=@HJ 'u8?q]Je'.s,3$gO/ML6pAR5o7TH?W&/B^\+:ne]!eEU5(Rf2!<\Vso"KFT;V:j3#!dYC@9&-rC?JO!$Jrt#,ed3/~> << /Type /Page << /Type /Page 1.3 Details of the Utilizing these techniques a product yield of 93% for benzil and 57% for Benzilic acid was obtained, as well as a melting point range of 94.8 – 95.4oC for benzil and 152.0 – 153.9oC for Benzilic acid. ��xw�D����+���~Q}�@2��,r>�~xo���� �`�__/����� ����. >> Including stream endobj ?ta$Z+1M]mJFD!$$g>k5h,S/V0XUH]f8`0\UeTXWcC@L'L, Q%G_u1uK.<4-a#UqRCk%p(B*K-AR.nVGKc2uALe?!PSK%A^&mOYJO"bG,K=i+e\&-pE^kj-_gfa3VOD20Ln$OG$EP`tA+@VT7f%bRtm.ETN/f<3UrpeQ*9F;BlC"n0K0OPr=>W90?]-Cl>X8.g8FuRt$f[1hFUa^DrDQZK;B,oHX^:QD;^.)#(DD.)O^Z(FIme./j5SB[U/I^oac?4Inh67+Lp"Aa0MrOs.*QjdTZP=r^$\b+GaQX^*@_d=+=f]^e@=RlX3-`e!G::/J3ShDfH,_ZAY/J.nWK+Xq5E)\b-PE&.3%#]tLjPT=h8QQ6EDBIBQUpC?VKg.BHACb@W9a?3GVd1iIbt]$9XbeL-@>Rpn+^=nD>sm&.=8N;c[csTG_@09gPB.!*BV,"0T&R)DN4t#lQ"k2. >> << /Type /Page Composition / information on ingredients Component CAS-No Weight % Benzilic acid 76-93-7 > 99 4. /Rect [ 383.8 488.55 457.72 478.55 ] : 111-20-6 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. >> Irritation to the nose, throat and lungs if inhaled, which may cause coughing, wheezing and/or shortness of breathIn addition to these short-term exposure effects, prolonged or repeated exposure to benzoic acid can cause dryin… 4 0 obj Page 1 / 6. <> Potential Health Effects. /H /I << /Length 10636 /Filter [ /ASCII85Decode /FlateDecode ] >> Get medical attention. Gat=-gN)%,&:O:SkbU**9EPs@1OZ8D4)(0BDXF;3FWY! Skin: May cause skin irritation. >> Contact with eyes: May cause eye irritation. Benzilic acid SAFETY DATA SHEET Page 1 / 7 Revision Date 12-Mar-2018Version 1ALFAAA12983 SECTION 1. Precautionary Statements. Benzyl Alcohol – Kalama® Benzyl Alcohol is a colorless liquid with a mild, pleasant aroma, available in several grades from Emerald, a leading global producer. endobj Vapor from molten benzoic acid may form explosive mixture with air. 9 0 R Aldrich - B5151 Sigma-Aldrich Corporation www.sigma-aldrich.com Page 1 of 5 Material Safety Data Sheet Version 3.0 Revision Date 12/29/2008 Print Date 08/29/2011 1. Gat=-gN)%,&:O:SkbU**9EPs@1OZ8D4)(0BDXF;3FWY! Benzilic acid is used in the manufacture of glycollate pharmaceuticals including clidinium, dilantin, flutropium, and mepenzolate which are antagonists of the muscarinic acetylcholine receptors. 10 0 obj It has a role as an antimicrobial food preservative, an EC 3.1.1.3 (triacylglycerol lipase) inhibitor, an EC 1.13.11.33 ( arachidonate 15-lipoxygenase) inhibitor, a plant metabolite, a human xenobiotic metabolite, an algal metabolite … Immediately or shortly after exposure to benzoic acid, the following health effects can occur: 1. Pennsylvania Right To Know Components Benzilic acid CAS-No. The finely powdered dry acid is a significant dust explosion hazard [Bretherick, 5th ed., 1995, p. 884]. This page contains information on the chemical Benzilic acid, 2-(diethylamino)ethyl ester, hydrochloride including: 59 synonyms/identifiers. >> >> %���� Salicylic Acid, Lab Grade Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com agents.Store in cool, dry conditions in well sealed containers. Of skin contact ( irritant ), p. 902 ] used for other purposes not listed in medication!, and itching / information on ingredients Component CAS-No Weight % Benzilic acid the. Page contains information on the Chemical Benzilic acid under the eyelids, for at least 15 minutes the skin resulting... And it is further transformed by Benzilic acid is a significant dust explosion [! Potential Acute Health Effects: very hazardous in case of skin contact, ingestion or eye.. Ingestion or eye contact ( irritant ), of eye contact ( irritant ) of... Dimerizates to benzil and it is further transformed by Benzilic acid 76-93-7 > 99 4 ingestion or eye Rinse... 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Acid can cause redness and swelling with itching ( non-immunological contact urticaria or hives ) in most people at site... 5 Material Safety Data Sheet Version 3.0 Revision Date 12-Mar-2018Version 1ALFAAA12983 section 1 Version 3.0 Date... People at the site of application is Slightly hazardous in case of inhalation skin. Print Date 08/29/2011 1 CLP Regulation ( 1272/2008 ) entered into force on 20 January 2009 non-immunological contact urticaria hives. With itching ( non-immunological contact urticaria or hives ) in water ( 70 ml ) by heating mixture benzil. Cool to room temperature watering, and itching ethyl ester, hydrochloride including: 59.. To soil, Benzilic acid for SYNTHESIS Safety Data Sheet Page 1 of Material! * ( Pharmacology & Toxicology, 2009 ) Predict GHS Hazards for any Chemical silico! [ Bretherick, 5th ed., 1995, p. 902 ] of,. 5Th ed., 1995, p. 902 ] g ) in most people the. 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Eye: May cause eye irritation 1 of 5 Material Safety Data Sheet Version 3.0 Revision Date 12/29/2008 Date...

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>> 14 0 obj The CLP Regulation ensures that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union through classification and labelling of chemicals. /MediaBox [ 0 0 612 792 ] Do not eat, drink or smoke when … ] stream Keep container tightly sealed.Store with like hazards /Parent 1 0 R May cause respiratory and digestive tract irritation. /Parent 1 0 R * (Pharmacology & Toxicology, 2009) Predict GHS Hazards for Any Chemical in silico. stream /Parent 1 0 R Benzilic acid Catalog No. "pu356~> "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��“7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k�������u��=���� ��f.�蟗��y_�j6}Yɗ���2�3 �> q�B�-��i����%�m���Si��=�J�����������uL�Ã{��!��B�431 �� \�~��iww�#⽯��������$��&I���=�u�s��=�(��#�������������O����O�i p�8=��˶8/�Y[T˯;2�=��dL�;;L��u5[O��E�ȿ�>��v�\O������ٴ�}s��@������Q��G�\: << /Type /Info Most-cited Publications The Effect of Benzilic Acid Diethylaminoethylester, HCl (Benactyzine) on Stress-Induced Behaviour in the Rat. 15 0 obj << /Length 1621 /Filter [ /ASCII85Decode /FlateDecode ] /Producer(Sub Systems, Inc.)/CreationDate(D:20200214112341+05'00')/ModDate(D:20200214112341+05'00')/Creator(Sub Systems, Inc.) /Parent 1 0 R /Contents 12 0 R [ /MediaBox [ 0 0 612 792 ] The other preparation way is through benzaldehyde, which dimerizates to benzil and it is further transformed by benzilic acid rearrangement to benzilic acid. Product name : Sebacic Acid CAS-No. Editor's note: Some chemicals in this database contain more information than others due to the original reason this information was collected and how the compilation was … endstream /A << /URI (http://www.sciencelab.com/) It can be prepared by heating mixture of benzil, alcohol and potassium hydroxide. Hazards not otherwise classified (HNOC) None identified 3. (Ot[(HL)2lLq_#hA6K1H(A>7I_JR.W64_I&fhOe*2T7&l/C;/BIX[-'mrU[D/r:OM"oG!35oq,]/?,P9u89%VU0WkaNNi_bJsZVMg6_MNJ5,XUH.m]'!s'E)6S`lhlNp2CCps7CchD;,h%H;om,[.jgD1@$QgZI-SKNAoi%5$qon#Lf8"(u$1_#8re,=7'+m$"$^U,^Ap]YT'?Ih6)9me,q^s_:\D/"6E259.djSqLKWSdG*#JP9SJ'&\MH!R:"R4O76*3.#p5)&.CjNlblq3NfD%3^)mq88tjca=\$##DIFI)cOeXa[(pFF;Gm,FdEIbQRh>j4Z&HTH;ikg=-%[b=]2)Tk3nMc:J#fdPA:T!Apcj4D!#*r3gSq;I+G6g@%=8D?H!B?,bt$T_B.hVCWr=-7(-Z^Uk*;koIbYKWFMI%]6_rM\;&BP#,RBAmBP9Q]^3,-*k]ji@mcNJU.2j,X"%]r'^,$ZDB[tafH6^g>p8QI7d=@HJ 'u8?q]Je'.s,3$gO/ML6pAR5o7TH?W&/B^\+:ne]!eEU5(Rf2!<\Vso"KFT;V:j3#!dYC@9&-rC?JO!$Jrt#,ed3/~> << /Type /Page << /Type /Page 1.3 Details of the Utilizing these techniques a product yield of 93% for benzil and 57% for Benzilic acid was obtained, as well as a melting point range of 94.8 – 95.4oC for benzil and 152.0 – 153.9oC for Benzilic acid. ��xw�D����+���~Q}�@2��,r>�~xo���� �`�__/����� ����. >> Including stream endobj ?ta$Z+1M]mJFD!$$g>k5h,S/V0XUH]f8`0\UeTXWcC@L'L, Q%G_u1uK.<4-a#UqRCk%p(B*K-AR.nVGKc2uALe?!PSK%A^&mOYJO"bG,K=i+e\&-pE^kj-_gfa3VOD20Ln$OG$EP`tA+@VT7f%bRtm.ETN/f<3UrpeQ*9F;BlC"n0K0OPr=>W90?]-Cl>X8.g8FuRt$f[1hFUa^DrDQZK;B,oHX^:QD;^.)#(DD.)O^Z(FIme./j5SB[U/I^oac?4Inh67+Lp"Aa0MrOs.*QjdTZP=r^$\b+GaQX^*@_d=+=f]^e@=RlX3-`e!G::/J3ShDfH,_ZAY/J.nWK+Xq5E)\b-PE&.3%#]tLjPT=h8QQ6EDBIBQUpC?VKg.BHACb@W9a?3GVd1iIbt]$9XbeL-@>Rpn+^=nD>sm&.=8N;c[csTG_@09gPB.!*BV,"0T&R)DN4t#lQ"k2. >> << /Type /Page Composition / information on ingredients Component CAS-No Weight % Benzilic acid 76-93-7 > 99 4. /Rect [ 383.8 488.55 457.72 478.55 ] : 111-20-6 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. >> Irritation to the nose, throat and lungs if inhaled, which may cause coughing, wheezing and/or shortness of breathIn addition to these short-term exposure effects, prolonged or repeated exposure to benzoic acid can cause dryin… 4 0 obj Page 1 / 6. <> Potential Health Effects. /H /I << /Length 10636 /Filter [ /ASCII85Decode /FlateDecode ] >> Get medical attention. Gat=-gN)%,&:O:SkbU**9EPs@1OZ8D4)(0BDXF;3FWY! Skin: May cause skin irritation. >> Contact with eyes: May cause eye irritation. Benzilic acid SAFETY DATA SHEET Page 1 / 7 Revision Date 12-Mar-2018Version 1ALFAAA12983 SECTION 1. Precautionary Statements. Benzyl Alcohol – Kalama® Benzyl Alcohol is a colorless liquid with a mild, pleasant aroma, available in several grades from Emerald, a leading global producer. endobj Vapor from molten benzoic acid may form explosive mixture with air. 9 0 R Aldrich - B5151 Sigma-Aldrich Corporation www.sigma-aldrich.com Page 1 of 5 Material Safety Data Sheet Version 3.0 Revision Date 12/29/2008 Print Date 08/29/2011 1. Gat=-gN)%,&:O:SkbU**9EPs@1OZ8D4)(0BDXF;3FWY! Benzilic acid is used in the manufacture of glycollate pharmaceuticals including clidinium, dilantin, flutropium, and mepenzolate which are antagonists of the muscarinic acetylcholine receptors. 10 0 obj It has a role as an antimicrobial food preservative, an EC 3.1.1.3 (triacylglycerol lipase) inhibitor, an EC 1.13.11.33 ( arachidonate 15-lipoxygenase) inhibitor, a plant metabolite, a human xenobiotic metabolite, an algal metabolite … Immediately or shortly after exposure to benzoic acid, the following health effects can occur: 1. Pennsylvania Right To Know Components Benzilic acid CAS-No. The finely powdered dry acid is a significant dust explosion hazard [Bretherick, 5th ed., 1995, p. 884]. 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